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  • 1
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Mass-separated 56Fe+ ions were implanted into Si(100) at 350 °C using three different energies and doses of 140 keV (1.32×1017 cm−2), 80 keV (6.20×1016 cm−2), and 50 keV (3.56×1016 cm−2). Their optical properties were investigated as a function of subsequent annealing temperature and its duration time. X-ray diffraction analysis revealed that polycrystalline semiconducting β-FeSi2 layers are formed in the as-implanted and annealed samples. From Rutherford backscattering spectrometry analysis, the formation of β-FeSi2 up to the surface was confirmed, and the average thickness and composition of the layers at peak concentration were estimated to be 70–75 nm and Fe:Si=1:2.0–2.2, respectively. The types of optical transition and the inverse logarithmic slope (E0) of the Urbach tail were investigated using room temperature optical absorption measurements. All the synthesized β-FeSi2 layers exhibited a direct transition with direct band-gap energies (Egdir) of 0.802–0.869 eV and with high optical absorption coefficients extending to 105 cm−1 at photon energy above 1.0 eV. The E0 value characteristic of the Urbach tail was observed to decrease from 260 to 100 meV with elevating annealing temperature. Some of the materials having E0〈160 meV showed two strong photoluminescence (PL) emissions peaked at 0.805–0.807 eV (No. 1) and 0.840–0.843 eV (No. 2) at 2 K, whereas those with E0(approximately-greater-than)250 meV exhibited only weak emissions. From the results of the temperature- and excitation power-dependent PL measurements, emissions Nos. 1 and 2 were attributed to the trap-related recombinations related to β-FeSi2, with thermal activation (quenching) energies of 54.7 and 46.7 meV, respectively. © 1996 American Institute of Physics.
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  • 2
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 81 (1997), S. 2794-2798 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Cu-rich CuGaSe2 films grown on [001] oriented GaAs substrates by molecular beam epitaxy show a remarkable low temperature photoluminescence emission peaked at 1.620 eV. This emission can be attributed to a free-to-bound recombination accompanying a donor-to-acceptor pair recombination. The ionization energies of these states are found to be 3.4 and 108 meV, respectively, via temperature dependent photoluminescence. The 108 meV state is attributed to a donor and the 3.4 meV state to an acceptor state observed. © 1997 American Institute of Physics.
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  • 3
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Slightly Cu-rich CuGaSe2 films were grown on [001] oriented GaAs substrates by molecular beam epitaxy. Photoluminescence of the films showed a remarkable emission peaked at 1.71 eV at low temperature, which is attributed to recombination of free excitons and bound excitons. The dissociation energy of free excitons and their localization energy to a center are found to be 16.2 and 3.3 meV, respectively. The band-gap energy Eg is estimated to be 1.7310 eV at low temperature. It is suggested that the temperature variation of Eg is dominated by interaction with phonons of 26 meV which corresponds to the mean energy of the optical phonons in CuGaSe2. © 1996 American Institute of Physics.
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  • 4
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The effects of residual ion damage in low-energy (30 eV–30 keV) C+-doped GaAs were investigated with regard to the electrical and optical activation of C as a function of C+ ion acceleration energy EC+. Systematic variation of EC+ demonstrated that, in the energy range of EC+〈170 eV, the net hole concentration (|NA−ND|) slightly increases as EC+ increases and the highest |NA−ND| was obtained at EC+=170 eV under the constant C+ ion-beam current density. For EC+(approximately-greater-than)170 eV, an increase in EC+ gave rise to an abrupt decrease of |NA−ND| down to two orders of magnitude smaller than that obtained at EC+=170 eV. In low-temperature (2 K) photoluminescence spectra for as-grown samples with EC+=240 and 350 eV, a novel emission ascribable to residual ion damage was observed instead of an essential acceptor–acceptor emission of [g−g]β. However, subsequent annealing at 850 °C made this novel emission disappear and the proper [g−g]β emission was merely observed. An activation process observed for EC+=5, 10, and 30 keV samples was very similar to that by high-energy ion implantation, indicating low activation rate of 10%–15%. Minority-carrier lifetime measurements using scanning tunneling microscope stimulated time-resolved luminescence demonstrated the presence of residual ion damage in as-grown samples at EC+=240 and 350 eV and annealed ones at EC+=5, 10, and 30 keV while no ion damage was observed in as-grown sample at EC+=30 eV. The incorporation and activation behaviors of C atoms that take the form of low-energy ions were found to be considerably affected by changes in ion–surface interaction with increasing EC+ and by the presence of residual ion damage in the layer. © 1996 American Institute of Physics.
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  • 5
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 77 (1995), S. 4828-4830 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Low-temperature photoluminescence experiments were carried out for Sr+ ion-implanted GaAs substrates as a function of Sr concentration and excitation intensity. It was found that the Sr impurity produces four emissions denoted by (Sr°, X), "G1'', "G2'', and "H'' in the near band emission region in GaAs grown by molecular beam epitaxy. "G1'' emission presents a red shift with increasing Sr concentration, while "G2'' does not shift. In a Sr+ ion-implanted impure GaAs substrate grown by the liquid-encapsulated Czochralski method, all four of the above emissions were missing. Instead there appeared two other emissions, SM1 and SM2, which are considered to be related to two deep acceptor levels of Sr in GaAs. All results indicate that the Sr impurity produces both shallow and deep energy levels in GaAs and a small amount of the residual impurity will quench the emissions related to shallow energy levels. © 1995 American Institute of Physics.
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  • 6
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: A combined ion-beam and molecular-beam-epitaxy (CIBMBE) system has been developed. This system consists of an ion implanter capable of producing ions in the energy range of 30 eV–30 keV and conventional solid-source MBE. As a successful application of CIBMBE, low-energy (100 eV) carbon ion (C+) irradiation during MBE growth of GaAs was carried out at substrate temperatures Tg between 500 and 590 °C. C+-doped layers were characterized by low-temperature (2 K) photoluminescence (PL), Raman scattering, and van der Pauw measurements. PL spectra of undoped GaAs grown by CIBMBE revealed that unintentional impurity incorporation into the epilayer is extremely small and precise doping effects are observable. CAs acceptor-related emissions such as "g,'' [g-g], and [g-g]β are observed and their spectra are significantly changed with increasing C+ beam current density Ic. PL measurements showed that C atoms were efficiently incorporated during MBE growth by CIBMBE and were optically well activated as an acceptor in the as-grown condition even for Tg as low as 500 °C. Raman measurement showed negligible lattice damage of the epilayer bombarded with 100 eV C+ with no subsequent heat treatment. These results indicate that contamination- and damage-free impurity doping without postgrowth annealing can be achieved by the CIBMBE method. © 1995 American Institute of Physics.
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  • 7
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Radiative mechanism of a newly discovered near-band-edge emission, [g-g], exclusively associated with acceptor impurities in GaAs, was theoretically discussed. Since the emission energy of [g-g] for the lowest acceptor concentration limit is nearly identical to that of the excited state of the acceptor impurities and it shows a noticeable shift towards lower-energy levels with increasing acceptor concentration, it was suggested that the energy of [g-g] corresponds to the 2pσ bond state of the acceptor-acceptor pair formed by the overlapping of the 2p excited state. The calculated energy of the 2pσ bond as a function of the distance between the acceptor-acceptor pair shows good agreement with the experimentally obtained value of [g-g] in Mg-doped GaAs grown by molecular-beam epitaxy (MBE). From a comparison of binding energies in the acceptor-doped GaAs samples prepared by ion implantation (Zn+ or Mg+) and by MBE, the activation ratio of the implanted atoms was estimated.
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  • 8
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Liquid-phase epitaxy (LPE) of Mg-doped GaAs was carried out. An extremely heavy doping was accomplished with a maximum net hole concentration of 1.31×1019 cm−3. A systematic investigation of photoluminescence spectra was performed as a function of hole concentration, which revealed that a newly discovered emission characterizing acceptor impurities can be obviously recognized also in LPE-grown samples in spite of the fact that the selective optical compensation effect among doped acceptors and residual donors presumably coming from Si of the LPE quartz tube is supposed to be comparatively strong. The red shift of this emission energy with increasing hole concentration and its locking at high hole concentration were discussed theoretically by introducing a preliminary model, i.e., a pair between excited-state acceptors.
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  • 9
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Newly discovered Zn-associated emissions in GaAs, "g'' and [g-g], were found to be completely suppressed by the simultaneous presence of Zn and Se atoms. This selective optical compensation (SOC) effect observed when acceptor (Zn) and donor (Se) atoms exist in combination was established by simultaneously implanting Zn+ and Se+ ions into almost carbon-free ultrapure GaAs made by molecular-beam epitaxy. It is suggested that the failure to observe "g'' and [g-g] emissions in acceptor-incorporated GaAs prepared by conventional epitaxial methods may be ascribed to this SOC effect, in which donor atoms were unintentionally introduced into the epitaxial layer.
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  • 10
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: A drastic change of the conduction type from p to n with an increase of the As4 to Ga flux ratio, γ, was observed for the first time in the photoluminescence spectra of amphoteric impurity (Ge)-doped GaAs made by molecular-beam epitaxy. The sample with the lowest γ (γ=1.0) presented a purely p-type emission associated with pairs between the excited states of acceptors. The sample with the highest γ (γ=10.6) indicated a totally n-type emission reflecting an increase of quasi Fermi energy. Results show that by precisely controlling the flux ratio, γ, one can reliably make use of substantially amphoteric atoms of Ge both as p- and n-type impurities for the fabrication of GaAs by molecular-beam epitaxy.
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