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  • 1
    ISSN: 1432-1866
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract Whole rock oxygen isotope data are presented for the Panorama district, in the Archean Pilbara Craton of Western Australia, where near-perfect exposure reveals a cross section through a complete volcanogenic massive sulfide (VMS) hydrothermal alteration system. The δ18O values decrease with depth in the volcanic pile, across semi-conformable alteration zones, to values below 6‰ immediately above a large (180 km2) subvolcanic intrusion. Altered rocks in the upper parts of the subvolcanic intrusion have lower δ18O values (6–8‰) than least altered granite (8‰), apart from sericite–quartz altered zones, which are slightly higher (8–10‰). Corridors of low δ18O values crosscut this regional zonation, and are coincident with transgressive feldspar-destructive alteration zones, which underlie VMS mineralization. The whole rock oxygen isotope distribution patterns are interpreted to represent alteration temperature, where high δ18O values correspond to low temperature alteration and low δ18O values correspond to high temperature alteration. Alteration temperatures, which were calculated using modal alteration mineral abundances and an assumed fluid δ18O, are consistent with this interpretation. Increasing temperatures with depth in the volcanic pile and high temperatures in transgressive corridors leading up to VMS deposits, are consistent with a convective hydrothermal model, in which heat from the subvolcanic intrusion drove seawater through the volcanic pile. Granite-hosted sericite–quartz alteration zones are 18O-enriched, and are tentatively interpreted to have formed from a mixed magmatic-evolved seawater fluid.
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  • 2
    ISSN: 1432-1866
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract Gold-copper-bismuth mineralization in the Tennant Creek goldfield of the Northern Territory occurs in pipe-like, ellipsoidal, or lensoidal lodes of magnetite ± hematite ironstones which are hosted in turbiditic sedimentary rocks of Proterozoic age. Fluid inclusion studies have revealed four major inclusion types in quartz associated with mineralized and barren ironstones at Ten nant Creek; (1) liquid-vapour inclusions with low liquid/vapour ratios (Type I), (2) liquid-vapour inclusions with high liquid/vapour ratios or high vapour/liquid ratios and characteristic dark bubbles (Type II), (3) liquid-vapour-halite inclusions (Type III), and (4) liquid-vapour inclusions with variable liquid/vapour ratios (Type V). Type I inclusions are present in the barren ironstones and the unmineralized portions of fertile ironstones, whereas Types II and III inclusions are recognized in fertile ironstones. Trails of Types II and III inclusions cut trails of Type I inclusions. Type I fluid inclusions have homogenization temperatures of 100° to 350 °C with a mode at 200° to 250 °C. Type II inclusions in mineralized ironstones (e.g. Juno, White Devil, Eldorado, TC8 and Gecko K-44 deposits) have homogenization temperatures of 250 °C to 600 °C with a mode of 350 °C. Type I fluid inclusions have a salinity range of 10 to 30 NaCl equiv. wt %. Salinity measurements on fluid inclusions in the mineralized zones gave a range of 10 to 50 NaCl equiv. wt % with a mode of 35 NaCl equiv. wt %. Fluid inclusion studies indicate that the Tennant Creek ironstones were formed from a relatively low temperature and moderately saline fluid, where as gold and copper mineralization was deposited from later hydrothermal fluids of higher temperature and salin ity. Gas analysis indicates the presence of N2 and CO2, with very minor CH4 in Types II inclusions but no N2 or CH4 gases in Type I inclusions. Microprobe analysis of the fluid inclusion decrepitates indicates that the inclusions from Tennant Creek contain sodium and calcium as dominant cations and potassium in a subordinate amount. The high temperatures (≥ 350 °C), high salinities (≥ 35 NaCl equiv. wt. %) and cation composition of the Tennant Creek ore fluids suggest that the ore fluids were derived from upward migrating heated basinal brines, although contribution from a magmatic source cannot be ruled out. Close association of vapour-rich Type IIb and salt-rich Type III inclusions in the mineralized ironstones (e.g. Juno, White Devil, Eldorado, TC8 and Gecko K-44) indicates heterogeneous trapping of ore fluids. This heterogeneous trapping is interpreted to be due to unmixing (exsolution) of a gas-rich (e.g. N2) fluid during the upward migration of the metal bearing brines and/or due to degassing caused by reaction of oxidized ore fluids and host ironstones. Fluid inclusion data have important implications regarding the deposition of gold in the ironstones, and may have application in discriminating fertile from barren ironstones.
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Mineralium deposita 29 (1994), S. 275-287 
    ISSN: 1432-1866
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract Quartz-feldspar porphyry dikes in and around the White Devil ore deposit are weakly to strongly altered, with weakly altered cores grading outward toward intensely chloritized marginal zones in contact with massive ironstone or chlorite altered sediments. Petrographic studies indicate the following sequence of alteration: sericitization of the groundmass, sericitization and chloritization of feldspar phenocrysts, chloritization of the groundmass, and alteration of igneous biotite to hydrothermal biotite and then to chlorite, intense chloritization of the groundmass as to remove quartz, and, finally, destruction of quartz phenocrysts. Isocon analyses of whole rock geochemical data from altered porphyry indicate the following relative changes during alteration: (1) consistent, near total losses of Na and Pb, (2) increasing gains of Mg, Fe, Mn and Zn, and increasing losses of Si and Sr with increasing alteration intensity, (3) gains of Ti, Cr and U, and losses of K and Rb upon alteration of feldspar phenocrysts, and (4) losses of Zr, Nb, Y and Th upon the loss of quartz in the groundmass. Of the elements studied only Ca, Al and P did not undergo significant relative changes. “Immobile” elements such as Ti, Zr, Nb, Y and Cr are highly mobile during the most intense alteration of the White Devil porphyry. Based on evidence from field relationships, alteration studies and petrographic observations, the quartz-feldspar porphyry dikes intruded after the formation of ironstones, but prior to Au-Cu-Bi mineralization. This conclusion is consistent with previous interpretations by Nguyen et al. (1989) and Edwards et al. (1990), but inconsistent with the interpretation by McPhie (1993) that quartz-feldspar porphyry sills at the Peko smelter site intruded into wet sediments. Two or more periods of quartz-feldspar porphyry intrusion occurred in the Tennant Creek district.
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  • 4
    Publication Date: 2012-12-20
    Description: The ~3240 Ma Panorama volcanic-hosted massive sulfide (VHMS) district is unusual for its high degree of exposure and low degree of postdepositional modification. In addition to typical seafloor VHMS deposits, this district contains greisen- and vein-hosted Mo-Cu-Zn-Sn mineral occurrences that are contemporaneous with VHMS orebodies and are hosted by the Strelley granite complex, which also drove VHMS circulation. Hence the Panorama district is a natural laboratory to investigate the role of magmatic-hydrothermal fluids in VHMS hydrothermal systems. Regional and proximal high-temperature alteration zones in volcanic rocks underlying the VHMS deposits are dominated by chlorite-quartz ± albite assemblages, with lesser low-temperature sericite-quartz ± K-feldspar assemblages. These assemblages are typical of VHMS hydrothermal systems. In contrast, the alteration assemblages associated with granite-hosted greisens and veins include quartz-topaz-muscovite-fluorite and quartz-muscovite (sericite)-chlorite-ankerite. These vein systems generally do not extend into the overlying volcanic pile. Fluid inclusion and stable isotope studies suggest that the greisens were produced by high-temperature (~590°C), high-salinity (38–56 wt % NaCl equiv) fluids with high densities (〉1.3 g/cm 3 ) and high 18 O (9.3 ± 0.6 ). These fluids are compatible with the measured characteristics of magmatic fluids evolved from the Strelley granite complex. In contrast, fluids in the volcanic pile (including the VHMS ore-forming fluids) were of lower temperature (90°–270°C), lower salinity (5.0–11.2 wt % NaCl equiv), with lower densities (0.88–1.01 g/cm 3 ) and lower 18 O (–0.8 ± 2.6 ). These fluids are compatible with evolved Paleoarchean seawater. Fluids that formed the quartz-chalcopyrite-sphalerite-cassiterite veins, which are present within the granite complex near the contact with the volcanic pile, were intermediate in temperature and isotopic composition between the greisen and volcanic pile fluids (T = 240°–315°C; 18 O = 4.3 ± 1.5 ) and are interpreted to indicate mixing between the two end-member fluids. Evidence of mixing between evolved seawater and magmatic-hydrothermal fluid within the granite complex, together with the lack of evidence for a magmatic component in fluids from the volcanic pile, suggest partitioning of magmatic-hydrothermal from evolved seawater hydrothermal systems in the Panorama VHMS system. This separation is interpreted to result from either the swamping of a relatively small magmatic-hydro-thermal system by evolved seawater or density contrasts precluding movement of magmatic-hydrothermal fluids into the volcanic pile. Variability in the salinity of fluids in the volcanic pile, combined with evidence for mixing of low- and high-salinity fluids in the massive sulfide lens, is interpreted to indicate that phase separation occurred within the Panorama hydrothermal system. Although we consider this phase separation to have most likely occurred at depth within the system, as has been documented in modern VHMS systems, the data do not allow the location of the inferred phase separation to be determined.
    Print ISSN: 0361-0128
    Topics: Geosciences
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  • 5
    Publication Date: 2014-09-04
    Description: How and when continents grew and plate tectonics started on Earth remain poorly constrained. Most researchers apply the modern plate tectonic paradigm to problems of ancient crustal formation, but these are unsatisfactory because diagnostic criteria and actualistic plate configurations are lacking. Here, we show that 3.5–3.2 Ga continental nuclei in the Pilbara Craton, Australia, and the eastern Kaapvaal Craton, southern Africa, formed as thick volcanic plateaux built on a substrate of older continental lithosphere and did not accrete through horizontal tectonic processes. These nuclei survived because of the contemporaneous development of buoyant, non-subductable mantle roots. This plateau-type of Archean continental crust is distinct from, but complementary to, Archean gneiss terranes formed over shallowly dipping zones of intraoceanic underplating (proto-subduction) on a vigorously convecting early Earth with smaller plates and primitive plate tectonics.
    Print ISSN: 0305-8719
    Electronic ISSN: 2041-4927
    Topics: Geosciences
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  • 6
    Publication Date: 2013-11-21
    Description: Review and analysis of initial lead isotope ratios from Archean volcanic-hosted massive sulfide (VHMS) and lode gold deposits and of neodymium isotopes from igneous rocks from the geologic provinces that host these deposits identifies systematic spatial and temporal patterns, both within and between the provinces. The Abitibi-Wawa subprovince of the Superior province is characterized by highly juvenile lead and neodymium. Most other Archean provinces, however, are characterized by more evolved isotopes, although domains within them can be characterized by juvenile isotope ratios. The analysis indicates that the endowment (measured as the quantity of metal contained in geologic resources per unit surface area) of VHMS and komatiite-associated nickel sulfide deposits is related to the isotopic character and, therefore, the tectonic history of provinces that host these deposits. Provinces with extensive juvenile crust have significantly higher endowment of VHMS deposits, possibly as a consequence of higher heat flow and extension-related faults. Provinces with evolved crust have higher endowment of komatiite-associated nickel sulfide deposits, possibly because such crust provided either a source of sulfur or a stable substrate for komatiite emplacement. In any case, initial radiogenic isotope ratios can be useful in predicting the endowment of Archean terranes for VHMS and komatiite-associated nickel sulfide deposits. Limited data suggest similar relationships may hold in younger terranes. Lead isotope data may provide constraints on supercraton reconstructions in the Archean as lead isotope systematics appear to be highly provincial. Similar isotope systematics between the Superior province and the Eastern Goldfields superterrane may indicate a linkage during the Neoarchean, consistent with the similar geologic and metallogenic histories of these provinces.
    Print ISSN: 0361-0128
    Topics: Geosciences
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  • 7
    Publication Date: 1999-07-01
    Print ISSN: 0361-0128
    Electronic ISSN: 1554-0774
    Topics: Geosciences
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  • 8
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  • 10
    Publication Date: 2002-07-01
    Print ISSN: 0361-0128
    Electronic ISSN: 1554-0774
    Topics: Geosciences
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