Publication Date:
2015-02-21
Description:
The title compounds, C13H13N3O2S·0.5H2O, (I), and C17H14ClN3OS, (II), are hydrazinecarbothioamide derivatives. Compound (I) crystallizes with two independent molecules (AandB) and a water molecule of crystallization in the asymmetric unit. The chromene moiety is essentially planar in moleculesAandB, with maximum deviations of 0.028 (3) and 0.016 (3) Å, respectively, for the carbonyl C atoms. In (II), the pyran ring of the chromene moiety adopts a screw-boat conformation and the phenyl ring is inclined by 61.18 (9)° to its mean plane. In the crystal of (I), bifurcated N—H...O and C—H...O hydrogen bonds link the two independent molecules formingA–Bdimers with twoR21(6) ring motifs, andR22(10) andR22(14) ring motifs. In addition to these, the water molecule forms tetrafurcated hydrogen bonds which alternately generateR44(12) andR66(22) graph-set ring motifs. There are also π–π [inter-centroid distances = 3.5648 (14) and 3.6825 (15) Å] interactions present, leading to the formation of columns along thec-axis direction. In the crystal of (II), molecules are linked by pairs of N—H...S hydrogen bonds, forming inversion dimers with anR22(8) ring motif. The dimers are linked by C—H...π interactions, forming ribbons lying parallel to (210).
Electronic ISSN:
2056-9890
Topics:
Chemistry and Pharmacology
,
Geosciences
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