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  • 1
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Polar research 1982 (1982), S. 0 
    ISSN: 1751-8369
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geography , Geosciences
    Notes: The Orustdalen Formation of Brøggerhalvaya is well exposed on two coastal sections and is 200–250 m thick. It consists dominantly of siliceous conglomerates and sandstones with subordinate shales and impure coal. One horizon low in the sequence yielded spores of uppermost Dinantian/lowermost Namurian age. Three sedimentary fades have been recognised. The fluvial channel facies (interbedded conglomerates and cross-stratified sandstones) are interpreted as braided stream deposits with flow directions to south and west. A shale facies, sometimes with drifted plant remains, is interpreted as overbank in origin. Highly quartzose, medium-to-coarse-grained, cross-stratified sandstones make up the reworked facies where palaeocurrents are bimodal or indicate movement to the NE. The Formation is thought to represent sediments shed from an early Carboniferous fault scarp eroding’a siliceous Lower Palaeozoic source terrain. The proximity of a nearby coastline led to the construction of fan deltas where fluvial deposits were reworked by waves and/or tides. Early diagenetic events include the local development of pyrite, kaolinite and calcite cements. Reddening’probably occurred during Middle Carboniferous times beneath an exposed land surface. Following burial, pressure solution and quartz cementation eliminated porosity at depths greater than 1000 m.
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  • 2
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Sedimentology 30 (1983), S. 0 
    ISSN: 1365-3091
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: Calcites and dolomites from the late Precambrian Bonahaven Formation of Scotland exhibit luminescence when MnCO3〉0.03 wt % (dolomite) or 〉0.06 wt % (calcite) and FeCO3〈2-2-5 wt % (dolomite). Comparison with other published data shows close similarity in the position of Fe-quenching in dolomite, but more variability in the position of Mn-activation in calcites and dolomites and the onset of Fe-quenching in calcites. These anomalies are thought to relate to chemical controls subsidiary to the dominant factors of Fe and Mn concentration. It is not practical to make a useful comparison between operating conditions of different luminescence instruments because of differences in design and an inability to measure routinely the current actually on the specimen surface.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Sedimentology 27 (1980), S. 0 
    ISSN: 1365-3091
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: Dolomitization in member 1 of the Dalradian Bonahaven Formation of Islay was sequential. The sediments studied are siliciclastic tidal flat deposits, which originally contained pebbles of ferroan dolomicrite and sandy dolomicrite (type 1 dolomite). Following burial, both dolomicrite and clay-stone pebbles, and possibly other carbonates, were replaced by coarser, fluid-inclusion-bearing, chemically zoned (type 2) dolomite. Ferroan, inclusion-free, intergranular dolomite (type 3) in sandstones may be synchronous with late zones of type 2 dolomite which it closely resembles. Cathodoluminescence and microprobe analyses of type 2 dolomite characterize four ubiquitous growth stages within which there was considerable fluctuation in Fe and Mn content. There was much variation between and within samples in terms of timing of nucleation, absolute speed of growth and relative growth rate of crystals. Type 2 dolomite displays two types of intracrystalline truncation surfaces explicable by dissolution followed by overgrowth, or by replacement by a moving solution film. Type A is characterized by a single later zone cutting across earlier ones along the line of an irregular truncation surface which developed from the edges of the crystals. In type B truncations it is the interior, rather than the edges of crystals which show truncation, the truncations forming smooth closed surfaces which enclose areas filled centripetally with new zones. In general, dolomite has a pronounced tendency to form crystal faces, and thus compromise crystal boundaries, during replacement as well as during cementation. Thus, if nucleation of crystals is restricted to the margins of an area to be replaced, replacive dolomite is capable of completely mimicking a vug-filling texture.
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  • 4
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Sedimentology 44 (1997), S. 0 
    ISSN: 1365-3091
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: The Xinmincun Formation forms the uppermost unit of a thick Neoproterozoic section which accumulated near the east margin of the North China Block and is overlain by two thin nearshore to continental formations below fossiliferous Lower Cambrian sediments. Although tectonically deformed, sedimentary structures are preserved undeformed on cleavage-parallel surfaces, and an 80 m section has been reconstructed by correlation across minor folds and faults in the Golden Stone beach area, 50 km NE of the city of Dalian, southern Liaoning province.The measured section shows 65 m of storm-dominated deposits, consisting of alternations of micrites and sharp-based graded intraclastic grainstone beds (tempestites), some with rudaceous, commonly erosional or guttered, bases. The top 15 m of section shows three alternations of similar subtidal lithofacies with partly to completely dolomitized peritidal deposits (laminated, sometimes fenestral and desiccated, micrite beds, and intraclastic rudite and grainstone beds). Tempestite beds become thinner and less abundant upwards towards a muddy upper shoreface zone. This environment was characterized in part by the occurrence of micrite with thin or streaky lamination (probable storm-resuspended sediment), interbedded tempestites, numerous erosion surfaces, and evidence of liquidization and sediment slumping into hollows.Molar tooth structures are widespread in micrite beds of the Xinmincun Formation and are present in lesser abundance in tempestites and liquefied channel-fills. Originally the structures were sub-vertical cracks, 1–20 cm long, tapering upwards and downwards. Subsequently they became filled with microspar cement and buckled rigidly during compaction of surrounding sediment during burial. Evidence of repeated episodes of cracking, presence of brecciated cracks and localization of cracking within beds, together with variable degree of development and variation of preferential alignment in plan indicates a mechanical origin. Crack generation may have been by seismic surface waves generated by movement along faults defining either the basin's margins or its internal structure, or possibly by wave action during storms. A seismic origin for molar tooth structure is consistent with other Neoproterozoic occurrences. Their preferential occurrence in Precambrian deposits arises from the relative rigidity of micritic sediment at this time related to lack of bioturbation, incipient cementation and possibly microbial binding.
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  • 5
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Sedimentology 34 (1987), S. 0 
    ISSN: 1365-3091
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: The dominantly shallow-marine Vendian succession of NE Spitsbergen contains distinctive types of carbonate rock. Limestones deposited before Vendian glaciation resemble those described from other Upper Proterozoic successions, being high in Sr and inferred to have been originally aragonitic, including the distinctive 5–10 Jim equant polygonal calcite of cemented shrinkage cracks. In contrast, manganoan stromatolitic limestones within marginal-marine glacial-outwash deposits, and consisting of micrite, microspar and fascicular-optic calcite are interpreted as originally calcitic. The restriction of primary marine calcite to cold seawater is comparable with Recent and Permian carbonates, although the Precambrian example formed in a sea diluted with meltwater.There is good textural preservation of relatively 18O-rich oolitic dolostones which were cemented in a supratidal environment by artesian fluids. Nevertheless, early diagenetic replacement is inferred, immediately prior to a glacial episode. Post-glacial dolostones are either replacive marine, or evaporative lacustrine, but share rather more negative δ18O values, closer to the mean of Late Precambrian dolostones.The heaviest oxygen isotope values constrain seawater δ18O to no more negative than — 2 to — 4SMOW. The main reason for the pronounced oxygen isotopic depletion of most Late Precambrian carbonates is their initial metastable mineralogy. The possibility of determining palaeolatitudes of the enigmatic widespread Late Proterozoic glaciations by isotopic analysis of freshwater periglacial calcareous precipitates is raised. Significant carbon isotope variations reflect changes in depositional water chemistry: some of these could be global in extent.
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  • 6
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 361 (1993), S. 601-602 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] Two billion years, from roughly the fiftieth to the nineteenth percentiles of Earth history, is the compass of the Proterozoic Eon. At its dawn was the great protracted period of formation of the continental crust. Its demise was hastened, so we believe, by the accumu-lation of oxygen in the ...
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  • 7
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 304 (1983), S. 714-716 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] The Vendian sequence of north-east Spitsbergen, unmetamorphosed and lacking penetrative deformation, contains diamictite-bearing stratigraphical units whose glacial origin has been well documented8,10-13. These are the Wilsonbreen Formation11-14 and the Petrovbreen Member8,9 of the Elbobreen ...
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  • 8
    Publication Date: 2010-06-21
    Description: Detailed monitoring of three drip sites in New St Michael's Cave, Gibraltar, reveals a strongly coherent seasonal pattern of dripwater chemistry despite each site having significantly different flow paths and discharge patterns. Calcite saturation is closely linked to regular seasonal variations in cave air pCO2 caused by seasonally reversing ventilation driven by temperature difference between the cave interior and the air outside. A coupled model of CO2 degassing and calcite precipitation links seasonal {delta}13C variations in coexisting dripwater, cave air CO2 and speleothem calcite to large variations in pCO2 that are driven by cave ventilation. The relationships between stable isotope ratios, Sr/Ca and speleothem fabrics across annually formed calcite laminae are consistent with a degassing-calcite precipitation process in which rapid degassing controls the {delta}13C of both drip water DIC and calcite whereas a much slower rate of calcite precipitation causes seasonal cycles of Sr in a more complex manner. By demonstrating the causes of laminated speleothem fabrics plus trace element and isotope cycles in modern speleothem from a closely monitored cave, this study provides clear links between the local microclimate and the proxy record provided by speleothem geochemistry. In Gibraltar, low cave air pCO2 in summer is unusual compared to what has been revealed by cave monitoring carried out elsewhere and shows that caution is needed when linking paired speleothem fabrics to specific seasons without knowledge of local processes operating in the cave.
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  • 9
    Publication Date: 2010-06-21
    Description: Seasonality is encoded in palaeoproxies of secondary cave mineral deposits (speleothems) and the code is becoming cracked. The petrology of calcite stalagmites from Obir, an Alpine (1100 m altitude), perennially wet cave, was characterized by optical and electron backscatter diffraction, and their chemistry by bulk ICP-MS analysis, ion microprobe and synchrotron-based micro-X-ray fluorescence. Vadose water penetrates 70 m through Triassic limestones (with some Pb-Zn mineralization) to the chamber Saulenhalle where the stalagmites were collected. Strong seasonal ventilation in the cave leads to low PCO2 in winter associated with falls in speleothem sulphate S and increase in {delta}13C values. All samples display autumnal event lamination defined by a narrow, optically visible zone with increases in trace element concentrations, within which synchrotron studies have resolved {micro}m-scale enrichments of Pb and Zn. Small-scale (10 {micro}m) lateral trace element variations reflect alternate flat faces and rough crystal edges, influenced by high Zn content. The elemental covariations are consistent with the transport of Pb, Zn, P, F, Br and I adsorbed onto organic colloids in dripwater, but the final deposition may have been from aerosols and we propose this as a new mechanism requiring further investigation. This study represents the most complete demonstration of how chemical variations are powerful expressions of seasonal cave physiology in humid temperate caves, including the contrast between summer and winter conditions, and the preservation of sub-weekly events during the autumn season.
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  • 10
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