ISSN:
0941-1216
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
α-Amidoalkylation of allyltrimethylsilane with (-)- and (+)-menthyl-2-(o-Chlorobenzoylamino)-2-halogenoethanoate (2, 4a and 4b) gave in the presence of zinc chloride, separable mixtures of the diastereomers (-)- and (+)-menthyl-2-(o-Chlorobenzoylamino)-4-pentenoate (5a, 5b and 6a, 6b). The absolute configurations of 5a, 5b and 6a, 6b were determined through conversion of 5a into S-(+)-norvaline hydrochloride.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/prac.19943360410
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