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  • 1
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 75 (1994), S. 7389-7393 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: The effects of image potential due to dielectric mismatch on electronic and shallow donor impurity states in quasi-one-dimensional GaAs-Ga1−xAlxAs quantum-well wires with rectangular cross section for both finite barrier and infinitely high barrier are investigated. The results have shown that, when the image potential is included, the variations in electronic energy level and impurity binding energy are considerable, especially when the cross-section dimensions of the quantum wire become small. The results also showed that the effects of the impurity ion image potential on impurity binding energy are much larger than those of electron image potential.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 85 (2002), S. 0 
    ISSN: 1551-2916
    Quelle: Blackwell Publishing Journal Backfiles 1879-2005
    Thema: Maschinenbau , Physik
    Notizen: Porous silicon nitride with macroscopically aligned channels was synthesized using a freeze-drying process. Freezing of a water-based slurry of silicon nitride was done while unidirectionally controlling the growth direction of the ice. Pores were generated subsequently by sublimation of the columnar ice during freeze-drying. By sintering this green body, a porous silicon nitride with high porosity (over 50%) was obtained and its porosity was controllable by the slurry concentration. The porous Si3N4 had a unique microstructure, where macroscopically aligned open pores contained fibrous grains protruding from the internal walls of the Si3N4 matrix. It is hypothesized that vapor/solid phase reactions were important to the formation mechanism of the fibrous grains.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 3
    Digitale Medien
    Digitale Medien
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 85 (2002), S. 0 
    ISSN: 1551-2916
    Quelle: Blackwell Publishing Journal Backfiles 1879-2005
    Thema: Maschinenbau , Physik
    Notizen: Porous ZrO2 ceramics were fabricated by compacting a fine ZrO2 powder, followed by pressureless sintering. Two unidirectional pressures of 30 and 75 MPa were used to prepare the green compacts. The strength and the fracture toughness of porous ZrO2 specimens sintered from the compacts prepared by 75 MPa were substantially higher than those by 30 MPa, especially for the specimens with low porosity. However, the corresponding Young's moduli were identical. This caused the strain to failure of these porous bodies to increase significantly with increasing compaction pressure. Microstructural analyses showed that a number of voids and small flaws existed in the green compacts prepared by the lower pressure, due to the agglomeration of fine ZrO2 grains. It was revealed that the ZrO2 agglomeration resulted in a localized nonuniform shrinkage and degraded the mechanical properties of porous ZrO2 ceramics.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 4
    Digitale Medien
    Digitale Medien
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 85 (2002), S. 0 
    ISSN: 1551-2916
    Quelle: Blackwell Publishing Journal Backfiles 1879-2005
    Thema: Maschinenbau , Physik
    Notizen: Porous silicon carbide (SiC) ceramics were fabricated by an oxidation-bonding process in which the powder compacts are heated in air so that SiC particles are bonded to each other by oxidation-derived SiO2 glass. Because of the crystallization of amorphous SiO2 glass into cristobalite during sintering, the fracture strength of oxidation-bonded SiC ceramics can be retained to a relatively high level at elevated temperatures. It has been shown that the mechanical strength is strongly affected by particle size. When 0.6 μm SiC powders were used, a high strength of 185 MPa was achieved at a porosity of ∼31%. Moreover, oxidation-bonded SiC ceramics were observed to exhibit an excellent oxidation resistance.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 5
    Digitale Medien
    Digitale Medien
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 83 (2000), S. 0 
    ISSN: 1551-2916
    Quelle: Blackwell Publishing Journal Backfiles 1879-2005
    Thema: Maschinenbau , Physik
    Notizen: A ZrB2–SiC composite was prepared from a mixture of zirconium, silicon, and B4C via reactive hot pressing. The three-point bending strength was 506 ± 43 MPa, and the fracture toughness was 4.0 MPa·m1/2. The microstructure of the composite was observed via scanning electron microscopy; the in-situ-formed ZrB2 and SiC were found in agglomerates with a size that was in the particle-size ranges of the zirconium and silicon starting powders, respectively. A model of the microstructure formation mechanism of the composite was proposed, to explain the features of the phase distributions. It is considered that, in the reactive hot-pressing process, the B and C atoms in B4C will diffuse into the Zr and Si sites and form ZrB2 and SiC in situ, respectively. Because the diffusion of Zr and Si atoms is slow, the microstructure (phase distributions) of the obtained composite shows the features of the zirconium and silicon starting powders.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 6
    Digitale Medien
    Digitale Medien
    Oxford, UK : Blackwell Science Inc
    Journal of the American Ceramic Society 88 (2005), S. 0 
    ISSN: 1551-2916
    Quelle: Blackwell Publishing Journal Backfiles 1879-2005
    Thema: Maschinenbau , Physik
    Notizen: Long crack R-curve of a porous Si3N4 with aligned fibrous grains was investigated, using a chevron-notched beam technique. A crack was constrained to propagate normal to the grain alignment. The crack growth resistance of aligned porous Si3N4 was much larger compared with that of dense Si3N4 ceramics. Microstructure observations showed that pullouts of fibrous grains in aligned porous Si3N4 markedly increased during crack propagation relative to those of dense Si3N4, due to the existence of pores. The efficient grain pullouts in porous Si3N4 increased the bridging stress at the crack wake.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 7
    Digitale Medien
    Digitale Medien
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 87 (2004), S. 0 
    ISSN: 1551-2916
    Quelle: Blackwell Publishing Journal Backfiles 1879-2005
    Thema: Maschinenbau , Physik
    Notizen: In this work, 800 ppm of Zr4+ dopants were added to Al2O3-5 vol% SiC particle composite. Zr4+ doping led to a weak Al2O3 grain-boundary bonding so that the fracture mode changed from transgranular in undoped composite to intergranular in Zr4+-doped composite. The fracture mode change increased the fracture toughness of the composite. Transmission electron microscopy and energy-dispersive spectroscopy examinations revealed that the weak grain-boundary bonding in the doped composite was caused by the segregation of Zr4+ and Si4+ ions at the Al2O3 grain boundary.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 8
    Digitale Medien
    Digitale Medien
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 86 (2003), S. 0 
    ISSN: 1551-2916
    Quelle: Blackwell Publishing Journal Backfiles 1879-2005
    Thema: Maschinenbau , Physik
    Notizen: Al2O3-5 vol% SiC particle composites doped with 800 ppm rare-earth impurities (Y3+, Nd3+, and La3+) were fabricated by hot-pressing at a temperature of 1550°C. Doping of rare-earth impurities in Al2O3-SiC composites led to a fracture- mode change from transgranular in dopant-free composites to intergranular in rare-earth-doped composites. The fracture mode change obviously increased the crack deflection so that the fracture toughness of rare-earth-doped composites was higher than that of the composites without dopants, especially for the Nd3+- and La3+-doped composites. It was found that the fracture-mode change originated from a weak grain-boundary bonding caused by co-segregation of the rare-earth dopants and Si4+ ions dissolved from the SiC particle surfaces.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 9
    Digitale Medien
    Digitale Medien
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 84 (2001), S. 0 
    ISSN: 1551-2916
    Quelle: Blackwell Publishing Journal Backfiles 1879-2005
    Thema: Maschinenbau , Physik
    Notizen: The mechanical properties of Al2O3-based porous ceramics fabricated from pure Al2O3 powder and the mixtures with Al(OH)3 were investigated. The fracture strength of the porous Al2O3 specimens sintered from the mixture was substantially higher than that of the pure Al2O3 sintered specimens because of strong grain bonding that resulted from the fine Al2O3 grains produced by the decomposition of Al(OH)3. However, the elastic modulus of the porous Al2O3 specimens did not increase with the incorporation of Al(OH)3, so that the strain to failure of the porous Al2O3 ceramics increased considerably, especially in the specimens with high porosity, because of the unique pore structures related to the large original Al(OH)3 particles. Fracture toughness also increased with the addition of Al(OH)3 in the specimens with higher porosity. However, fracture toughness did not improve in the specimens with lower porosity because of the fracture-mode transition from intergranular, at higher porosity, to transgranular, at lower porosity.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 10
    Digitale Medien
    Digitale Medien
    Oxford, UK : Blackwell Science Inc
    Journal of the American Ceramic Society 88 (2005), S. 0 
    ISSN: 1551-2916
    Quelle: Blackwell Publishing Journal Backfiles 1879-2005
    Thema: Maschinenbau , Physik
    Notizen: Metal Al particle surfaces were modified by fine γ-Al2O3 grains using a mixture of Al and Al(OH)3 powders, which was pressureless sintered at a temperature of 600°C in vacuum. All the constituents on original Al particle surfaces were transformed into γ-Al2O3 phase after sintering. No dense passive oxide layers on Al particle surfaces were formed even after the modified Al particles were exposed to oxidation environment. The modified Al particles could continuously react with pure water and generate hydrogen at room temperature. The present finding implies that metal Al could become hydrogen-generation material by surface modification.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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