ISSN:
0030-493X
Keywords:
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
A new radical cation having the methyl carbene type structure [CH3CHClH]+· has been characterized in the gas phase. It is readily generated by the dissociative ionization [CH3CHCICO2H]+· → CO2+[CH3CHCIH]+·. Its enthalpy of formation has been estimated to be 951 kJ mol-1, close to that of [CH3CH2CI]+·. The principal fragmentation characteristics (loss of HCl and Cl·) of the ion are discussed. A brief description of the bromo analogue [CH3CHBrH]+· is also given.
Additional Material:
5 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/oms.1210180506
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