Publication Date:
2012-08-09
Description:
The highest concentrations of metals (e.g., Cu, Au, Ag, Mo) in the Earth's crust are found in porphyry-type deposits. The metals are ultimately sourced from magmas, and appear to be concentrated hundred to thousand-fold from typical magmatic contents (ppm-ppb) in the exsolved volatile phase. To better quantify the purging and transport of metals, we develop a physical model of volatile evolution in an incrementally built upper crustal magma reservoirs that considers (1) partitioning of metals from the melt to an exsolved volatile phase, and (2) advection of the buoyant volatile phase using a single dimensionless parameter, the Péclet number (Pe; ratio of advection rate over diffusion rate). We propose that metal extraction and segregation from magmas can occur in 3 stages with different Pe: (1) during exsolution of the magmatic volatile phase in shallow, crystal-poor magma bodies (slow volatile advection; Pe ≪ 1), (2) during the growth of volatile channels that develop in the reservoir as crystallinity increases (Pe 〈 1), and (3) during advection in connected channels (rapid volatile advection, high Pe ≥ 1). For each stage, a metal enrichment factor can be calculated, allowing insight into the optimal conditions to maximize metal mass flux into the overlying hydrothermal system. The model predicts that the most efficient purging of metals occurs for magmas with intermediate volatile contents and is enhanced during late-stage magmatic activity, as the reservoirs reach high crystallinity and are not disturbed by volcanic venting, in agreement with natural observations suggesting that ore formation post-dates volcanic activity.
Electronic ISSN:
1525-2027
Topics:
Chemistry and Pharmacology
,
Geosciences
,
Physics
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