ISSN:
0009-2940
Keywords:
Wittig reaction
;
Rapid injection NMR
;
Dynamic NMR
;
Oxaphosphetanes
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The course of the Wittig reaction was investigated by rapid injection NMR spectroscopy. Rate constants for the formation of oxaphosphetanes were determined. A new dynamic equilibrium of oxaphosphetanes was observed for the first time. The solvent and substituent dependence of the new effect was investigated. By labeling various oxaphosphetanes with 13C and 17O the lithium salt dependence of the new equilibrium was shown. A lithium adduct of oxaphosphetanes under these conditions is proposed.
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19931261109
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