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  • 1
    Digitale Medien
    Digitale Medien
    Oxford, UK : Blackwell Publishing Ltd
    Journal of metamorphic geology 8 (1990), S. 0 
    ISSN: 1525-1314
    Quelle: Blackwell Publishing Journal Backfiles 1879-2005
    Thema: Geologie und Paläontologie
    Notizen: A combination of fluid inclusion, stable isotope and geochemical techniques has been used to study the nature of fluids present and their behaviour during Caledonian low-grade metamorphism of the Harlech Dome, north Wales. Fluid inclusion studies show that in most of the metasedimentary sequence the peak metamorphic fluid was an aqueous Na–K–Cl brine but in the graphitic Clogau Formation and in parts of the overlying Maentwrog Formation immiscible H2O-rich and CH4-rich fluids coexisted.Late-stage inclusions are of calcium-rich brine and a dilute aqueous fluid. The chemical composition of chlorite in metamorphic veins and rocks varies between different formations and quartz-oxygen isotopic compositions show considerable variation between different units. Both of these features are taken to indicate that there was little or no pervasive movement of fluid between different units at the peak of metamorphism. After the metamorphic peak there was focused flow of fluid upward through the sequence along fractures, in response to end-Caledonian uplift and unloading. Where the migrating fluid crossed the graphitic shales, interaction between the fluid and the shales gave rise to the formation of the auriferous veins of the Dolgellau Gold Belt. Subsequent to this mineralizing event there was widespread development of 18O-enriched calcites and micas.In the case of vein minerals it is possible that these crystallized directly from late-stage fluids at lower temperature than the quartz in the same veins. Alternatively, the original vein minerals may have re-equilibrated with later 18O-enriched or cooler fluid. In the case of muscovites in the rock matrix it is proposed that the isotopically heavy compositions are the result of re-equilibration of initially light grains with an introduced fluid, requiring considerable influx of fluid. This event may relate to either of two late-stage fluids observed as inclusions.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    Oxford, UK : Blackwell Publishing Ltd
    Journal of metamorphic geology 10 (1992), S. 0 
    ISSN: 1525-1314
    Quelle: Blackwell Publishing Journal Backfiles 1879-2005
    Thema: Geologie und Paläontologie
    Notizen: Quartz veins are developed in a wide range of metasediment types in the upper amphibolite facies rocks of Connemara, and attest to considerable migration of silica. Contrary to common assumptions, there is clear evidence that these veins do not primarily result from movement of fluid to regions of lower P–T down the regional geothermal gradient. Under amphibolite facies conditions, a dilute chloride fluid moving down temperature has the potential to alter 60g of plagioclase to muscovite for each gram of vein quartz precipitated, while cooling over the temperature interval from 650 to 500° C. The absence of significant metasomatic effects in the vein walls effectively precludes a simple origin from such through-flowing, externally derived fluids. The oxygen isotopic composition of matrix quartz shows considerable differences between different rock types (quartzite, pelite and marble), with a range of δ18OSMOW from c.+ 11.5% (quartzite) to + 18.5% (marble). In each rock type, vein quartz compositions closely match those of the matrix quartz. These results demonstrate the importance of local segregation processes in the formation of veins, and suggest that fluid convection cells were not developed during metamorphism on a scale larger than the individual sedimentary formations, if at all.Both oxygen isotope data and the absence of metasomatism indicate that veins form primarily by segregation of quartz from the host lithologies, with only a relatively minor component of through flow of externally derived fluid. Veins are clearly not the major pathways of metamorphic dewatering.It is proposed that abundant veins in the predominantly pelitic Ballynakill Formation formed during peak metamorphic D3 folding because the formation was embrittled by high fluid pressures but was capped by impermeable marble. Hence the pelitic formation fractured repeatedly and the pore fluid drained through the fractures to form veins, while irreversible loss through the rest of the succession was a much less important process.In the central mountains of Connemara, rather pure, unreactive quartzites are cut by widely spaced, laterally extensive quartz veins that are axial planar to D3 folds. These veins may mark pathways whereby metamorphic fluid made its way through the massive impermeable quartzite from lower parts of the nappe pile, but here too, oxygen isotope data indicate considerable segregation of locally derived quartz, reflecting the importance of pumping of fluid between wail rocks and fractures relative to the component of through flow.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 3
    ISSN: 1365-3091
    Quelle: Blackwell Publishing Journal Backfiles 1879-2005
    Thema: Geologie und Paläontologie
    Notizen: Carbonate concretions in the Lower Carboniferous Caton Shale Formation contain diagenetic pyrite, calcite and barite in the concretion matrix or in different generations of septarian fissures. Pyrite was formed by sulphate reduction throughout the sediment before concretionary growth, then continued to form mainly in the concretion centres. The septarian calcites show a continuous isotopic trend from δ13C=−28·7‰ PDB and δ18O=−1·6‰ PDB through to δ13C=−6·9‰ PDB and δ18O=−14·6‰ PDB. This trend arises from (1) a carbonate source initially from sulphate reduction, to which was added increasing contributions of methanogenic carbonate; and (2) burial/temperature effects or the addition of isotopically light oxygen from meteoric water. The concretionary matrix carbonates must have at least partially predated the earliest septarian cements, and thus used the same carbonate sources. Consequently, their isotopic composition (δ13C=−12·0 to −10·1‰ PDB and δ18O=−5·7 to −5·6‰ PDB) can only result from mixing a carbonate cement derived from sulphate reduction with cements containing increasing proportions of carbonate from methanogenesis and, directly or indirectly, also from skeletal carbonate. Concretionary growth was therefore pervasive, with cements being added progressively throughout the concretion body during growth. The concretions contain barite in the concretion matrix and in septarian fissures. Barite in the earlier matrix phase has an isotopic composition (δ34S=+24·8‰ CDT and δ18O=+16·4‰ SMOW), indicating formation from near-surface, sulphate-depleted porewaters. Barites in the later septarian phase have unusual isotopic compositions (δ34S=+6 to +11‰ CDT and δ18O=+8 to +11‰ SMOW), which require the late addition of isotopically light sulphate to the porewaters, either from anoxic sulphide oxidation (using ferric iron) or from sulphate dissolved in meteoric water. Carbon isotope and biomarker data indicate that oil trapped within septarian fissures was derived from the maturation of kerogen in the enclosing sediments.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 4
    ISSN: 1432-1866
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Geologie und Paläontologie
    Notizen: Abstract Galenas from the Llanrwst and Llanfair-Talhaiarn orefields in North Wales have a restricted range of Pb-isotope values. M1 and M2 mineralizations at Llanrwst are isotopically separate in 206Pb/204Pb versus 207Pb/204Pb space, while the isotopic composition of the M3 mineralization exceeds the combined M1 and M2 range. The lead source for the Llanrwst orefield is believed to be the underlying Ordovician volcanic arc material. Data from the related Llanfair-Talhaiarn orefield suggest lead was derived from the host Silurian sediments in addition to the Ordovician basement. The time separation of the M1 and M2 veins at Llanrwst has been calculated using μ and ω data from Dixon et al. (1990) at 11 Ma and 15 Ma respectively.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 5
    Digitale Medien
    Digitale Medien
    Springer
    Environmental geochemistry and health 13 (1991), S. 119-126 
    ISSN: 1573-2983
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Geologie und Paläontologie , Medizin
    Notizen: Abstract Flue gas desulphurisation (FGD) equipment to be fitted to UK coal-fired power stations will produce more than 0.8 Mtonnes of calcium sulphate, as gypsum. Most gypsum should be of commercial quality, but any low grade material disposed as waste has the potential to generate a range of sulphur gases, including H2S, COS, CS2, DMS and DMDS. Literature data from the USA indicates that well-oxidised waste with a high proportion of calcium sulphate (the main UK product of FGD) has relatively low emissions of sulphur gases, which are comparable to background levels from inland soils. However, sulphur gas fluxes are greatly enhanced where reducing conditions become established within the waste, hence disposal strategies should be formulated to prevent the sub-surface consumption of oxygen.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 6
    Digitale Medien
    Digitale Medien
    Springer
    Water, air & soil pollution 85 (1995), S. 1641-1646 
    ISSN: 1573-2932
    Schlagwort(e): sulphur isotopes ; δ34S ; catchment ; bulk precipitation ; throughfall ; soil water
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik
    Notizen: Abstract Sulphate concentrations and δ 34S ratios were monitored in bulk precipitation, spruce throughfall, and soil water (depth of 30 and 90 cm) at Červená jáma (CER) and Načetín (NAC), two severely polluted sites in the Czech Republic, between December 1992 and September 1994. Throughfall [SO4 2−], up to 80 mg L−1 in winter and as low as 7 mg L−1 in summer, was higher than [SO4 2−] in bulk precipitation (annual average 6 mg L−1). There was a distinct seasonaity in S isotope abundances, with lower δ34SBULK in summer (+4 per mil CER, + 6 per mil NAC) and lower δ34STF in winter (+3 per mil CER, +4 per mil NAC). Wintertime δ34SBULK was around +8 per mil at CER and +10 per mil at NAC, summertime δ34STF was close to +7 per mil at both sites. For only a 1- month period in spring, bulk precipitation S became isotopically lighter than throughfall S. Bulk precipitation data from CER were in good agreement with those from the nearby monitoring station Lesná (LES), typically differing by less than 10 mg L−1 and 2 per mil in [SO4 2−] and δ34S, respectively. Suction lysimeters (soil depth of 30 and 90 cm) yielded higher sulphate concentrations and lower δ34S ratios compared to both bulk and throughfall precipitation. Little seasonality was observed in [SO4 2−] at 30 cm (around 40 mg L−1); at 90 cm [SO4 2−] was higher in winter (70 mg L−1) than in summer (45 mg L−1). δ34S at 90 cm was 〈+5 per mil in 1993 and up to +7.5 in 1994, lower in the first year and higher in the second year compared to the depth of 30 cm. Sulphur fluxes at CER and NAC are characterized by distinct isotope compositions and can therefore be used to trace S pathways and transformations in the forest ecosystem.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 7
    Publikationsdatum: 2007-10-08
    Beschreibung: Isotopic compositions of sulphate ({delta}18O and {delta}34S) have been analysed in groundwaters from a karst aquifer in Xingwen, China to assess their use as indigenous tracers of different pollutant sulphate sources. Sulphate {delta}18O is highly effective at distinguishing sulphate from atmospheric acid rain' sources (higher {delta}18O values) from sulphate produced by aqueous pyrite oxidation (natural or acid mine drainage), which always has lower {delta}18O. The range of sulphate {delta}34S produced by aqueous oxidation of different pyrite sources is sufficiently wide to enable different natural and pollutant sulphate sources to be distinguished. Despite the fact that streams containing processing fines and pyrite mine drainage both derive sulphate from oxidation of ore materials, there is still a clear distinction in their sulphate {delta}34S. A combination of sulphur and oxygen isotopic measurements is thus highly effective at discriminating between all the sulphate sources to the karst aquifer and this indigenous tracer provides a powerful tool for assessing the impact of acid mine drainage on karst groundwater.
    Standort Signatur Erwartet Verfügbarkeit
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  • 8
    Publikationsdatum: 2007-10-08
    Beschreibung: Groundwater abstraction from the Triassic Sherwood Sandstone aquifer in the Selby area, Yorkshire, UK, has caused decline of the water level in the aquifer and groundwater quality problems such as high chloride and sulphate concentrations. Geochemical and isotopic analysis of groundwaters and groundwater modelling of an approximately 25 x 30 km area around Selby was carried out to understand the groundwater flow conditions and identify the source of saline water. Isotopic compositions ({delta}34S and {delta}18O) of seawater sulphate, Coal Measures brine and Permian evaporite sources do not match that associated with salinity in the Selby wellfield. Rather, the source of saline groundwater in the Selby wellfield matches the isotopic composition of Triassic evaporites in the overlying Mercia Mudstones. Steady-state groundwater flow modelling demonstrates that that majority of water abstracted from the Selby wellfield is balanced by recharge from the west of Selby at Brayton Barff, and from the Escrick and York moraines to the north. A small proportion of the abstracted water originates from leakage from the River Ouse through the confining layer as a result of drawdown in the Selby area. The development of a cone of drawdown centred on Selby has created a new E-W hydraulic gradient to the east of Selby, allowing water ingress from the east. Capture-zone analysis indicates that the four abstraction boreholes contaminated by saline water collect groundwater from the north to NE (i.e. from the direction of the boundary between the Sherwood Sandstone and the Mercia Mudstone), confirming that the source of salinity is likely to be the Mercia Mudstone evaporites.
    Standort Signatur Erwartet Verfügbarkeit
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  • 9
    Publikationsdatum: 2007-10-08
    Beschreibung: Tracer tests have been performed on the unsaturated zone of the East Yorkshire chalk aquifer, UK. Rapid tracer travel times through significant thicknesses of unsaturated chalk (15-38 m) indicate that bypass flow must occur through fractures. Transport processes in the unsaturated zone of the chalk aquifer thus have similarities to those in the vadose zone of more typically karstic limestone aquifers. Modelling of tracer breakthrough curves indicates that bypass flow is sufficiently rapid to significantly inhibit diffusional loss of tracer into the porous matrix of the chalk. The presence of rapid karstic bypass flow in the unsaturated zone of the chalk will limit the potential for attenuation of groundwater contaminants in this zone.
    Standort Signatur Erwartet Verfügbarkeit
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  • 10
    Publikationsdatum: 2013-05-24
    Beschreibung: A bstract : Aluminum-phosphate–sulfate (APS) minerals, formed during early diagenesis in relation to acid meteoric waters, are the main host of Sr and S in the Early–Middle Triassic continental sandstones of the Iberian Ranges (east of the Iberian Peninsula). The sources of these elements and the effects of paleoenvironmetal changes on these sources and on the formation of APS minerals during Early–Middle Triassic times, were established on the basis of Sr and S isotopic analyses. The S and Sr data ( 34 S V-CDT = +11 to +14 and 87 Sr/ 86 Sr = 0.7099–0.7247, respectively) can be interpreted as resulting from mixing of different sources. Strontium was sourced from the dissolution of pre-existing minerals like K-feldspar and clay minerals inherited from the source areas, causing high radiogenic values. However, the isotopic signal must also be influenced by other sources, such as marine or volcanic aerosol that decreased the total 87 Sr/ 86 Sr ratios. Marine and volcanic aerosols were also sources of sulfur, but the 34 S was lowered by dissolution of pre-existing sulfides, mainly pyrite. Pyrite dissolution and volcanic aerosols would also trigger the acid conditions required for the precipitation of APS minerals. APS minerals in the study area are found mainly in the Cañizar Formation (Olenekian?–Aegian), which has the lowest 87 Sr/ 86 Sr ratios. The lower abundance of APS minerals in the Eslida Formation (Aegian–Pelsonian) may indicate change in the acidity of pore water towards more alkaline conditions, while the increased 87 Sr/ 86 Sr ratios imply decreased Sr input from volcanic activity and/or marine aerosol inputs during Anisian times. Therefore, the decrease in abundance of APS minerals from the Early to Middle Triassic and the variations in the sources of Sr and S are indicative of changes in paleoenvironmental conditions during the beginning of the Triassic Period. These changes from acid to more alkaline conditions are also coincident with the first appearance of carbonate paleosols, trace fossils, and plant fossils in the upper part of the Cañizar Formation (and more in the overlying Eslida Formation) and mark the beginning of biotic recovery in this area. The presence of APS minerals in other European basins of the Western Tethys (such as the German Basin, the Paris Basin and the southeastern France and Sardinia basins) could thus also indicate that unfavorable environmental conditions caused delay in biotic recovery in those areas. In general, the presence of APS minerals may be used as an indicator of arid, acidic conditions unfavorable to biotic colonization.
    Print ISSN: 1527-1404
    Thema: Geologie und Paläontologie
    Standort Signatur Erwartet Verfügbarkeit
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