ISSN:
1573-9171
Keywords:
5-allyl-2,3,5-trichloro-4,4-dimethoxycyclopent-2-en-1-one
;
dimethylsulfoxonium methylide
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract Dimethylsulfoxonium methylide in DMSO initiates unusual oxidative skeletal transformations of trichlorocyclopentenone. Lactone, cyclic orthoester, and a number of by-products of hydrolysis, substitution, and reduction were isolated and characterized. The expected epoxide was obtained in low yield.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01430648
Permalink