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  • FTIR spectroscopy  (1)
  • Structure of molecules  (1)
  • United Nation rise  (1)
  • 1
    ISSN: 1572-879X
    Keywords: Fe‐ZSM‐5 ; carbon monoxide ; FTIR spectroscopy ; nitrates ; nitrogen monoxide ; selective catalytic reduction ; adsorption ; zeolites
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Adsorption of NO on Fe‐ZSM‐5 leads to formation of Fen+–NO (n = 2 or 3) species (1880 cm-1), Fe2+(NO)2 complexes (1920 and 1835 cm-1) and NO+ (2133 cm-1). Water strongly suppresses the formation of NO+ and Fen+(NO)2 and more slightly the formation of Fen+ –NO. Introduction of oxygen to NO converts the nitrosyls into surface nitrates (1620 and 1575 cm-1) and this process is almost unaffected by water. The nitrates are thermally stable up to ca. 300°C, but readily interact with propane at 200°C, thus forming surface C–H–N–O deposit (bands in the 1700–1300 cm-1 region). Here again, water does not hinder the process. The C–H–N–O deposit is relatively inert (it does not interact with NO or NO + O2 at ambient temperature) but, at temperatures higher than 250 °C, it is decomposed to NCO- species (bands at 2215 (Fe–NCO) and 2256 cm-1 (Al–NCO)). In the presence of water, however, the Fe–NCO species only are formed. At ambient temperature the NCO- species are inert towards NO and O2, but easily react with a NO + O2 mixture. The mechanism of the selective catalytic reduction of nitrogen oxides on Fe‐ZSM‐5 and the effect of water on the process are discussed.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Marine geophysical researches 19 (1997), S. 421-438 
    ISSN: 1573-0581
    Keywords: Mediterranean ridge ; United Nation rise ; mud diapirs ; mud volcanoes ; dome-like structures
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The Mediterranean Ridge is interpreted as a large accretionary complex, which originated due to the northern subduction of the African lithosphere below the Eurasian one and the partial collision of those two continents; more precisely, between the African and Aegean Microplates. The main goals of the UNESCO-TTR 5 (Training Through Research) cruise, carried out by several methods including high resolution seismic profiling, included the investigations of mud volcanoes, the distribution of the Messinian evaporites, and mapping the seafloor structures. The high resolution seismic data were confirmed with other geoacoustic methods as sidescan sonars (short-ORETECH and long-range OKEAN) and subbottom sampling. The area of investigation is designed to run parallel to the Mediterranean Ridge on the eastern end towards the Florence Rise, and is situated between the northern and southern deformation fronts of the ridge. The seismic data were preprocessed onboard (band pass filtering, horizontal stack and attenuation level) and predictive deconvolution. New mud volcanoes and structures were discovered at the western part of the target area, named 'United Nations (UN) Rise' to celebrate the fiftieth anniversary of the United Nations. With respect to fluid expulsion, three mud volcanoes were imaged, all of which show different backscattering characteristics. The investigated area shows complex structures and the UN area within the inner deformation front of the Mediterranean Ridge, is much more complicated. Some features are similar to mud volcanoes, but with some important differences. The typical characteristics of these features are a positive (up-doming) structure on the seafloor relief, no acoustically transparent zone, a strong low-frequency reflector (M-reflector?) down-bent near this object and some of these features are symmetrical. The Mud volcanism can exhibit itself only where the evaporitic layer is thin or absent. The mud volcanism on the Mediterranean Ridge reflects the general tectonic evolution of the accretionary complex presently progressing.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Chromatographia 14 (1981), S. 107-109 
    ISSN: 1612-1112
    Keywords: Gas-adsorption chromatography ; Structure of molecules ; Indane, methylindanes ; Chromatoscopy
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary A molecular statistical calculation of the retention volumes at zero surface coverage on graphitized thermal carbon black using the atom-atom approximation for the potential energy of intermolecular interaction between adsorbate and adsorbent has been carried out for different structure models of indane, 2-methylindane and 5-methylindane molecules. By comparing the results of the calculations with measured retention volumes, plausible models have been chosen for the structure of the molecules studied.
    Type of Medium: Electronic Resource
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