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Chromatoscopic determination of the geometric parameters of indane hydrocarbon molecules

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Summary

A molecular statistical calculation of the retention volumes at zero surface coverage on graphitized thermal carbon black using the atom-atom approximation for the potential energy of intermolecular interaction between adsorbate and adsorbent has been carried out for different structure models of indane, 2-methylindane and 5-methylindane molecules. By comparing the results of the calculations with measured retention volumes, plausible models have been chosen for the structure of the molecules studied.

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Authors and Affiliations

  1. Laboratory of Adsorption and Chromatography, Chemistry Department, M. V. Lomonosov State University of Moscow, 117234, Moscow, USSR

    L. D. Dimitrov, A. V. Kiselev & R. S. Petrova

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  1. L. D. Dimitrov
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  2. A. V. Kiselev
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  3. R. S. Petrova
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Dimitrov, L.D., Kiselev, A.V. & Petrova, R.S. Chromatoscopic determination of the geometric parameters of indane hydrocarbon molecules. Chromatographia 14, 107–109 (1981). https://doi.org/10.1007/BF02279521

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  • DOI: https://doi.org/10.1007/BF02279521

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