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Detailed balance in far-wing line shape theories: Comparisons between different formalisms (1995)

Ma, Q. ; Tipping, R. H. ; Hartmann, J.-M. ; [et al.]

College Park, Md. : American Institute of Physics (AIP)

The Journal of Chemical Physics 102 (1995), S. 3009-3010

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ISSN: 1089-7690

Source: AIP Digital Archive

Topics: Physics , Chemistry and Pharmacology

Notes: Comparisons are made between different methods of introducing the principle of detailed balance in far-wing line shape theories. In particular, it is shown that by symmetrizing the operators in the quasistatic formulation of Ma and Tipping [J. Chem. Phys. 95, 6290 (1991)], one can obtain the same results for the symmetrized matrix elements of the relaxation operator and their frequency detuning that were introduced in an ad hoc way in the resonant quasistatic formulations of Boulet and co-workers [J. Chem. Phys. 91, 2163 (1989); 94, 6406 (1991)]. © 1995 American Institute of Physics.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1063/1.468610

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