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Completely asymmetric nuclear quadrupole effects on electron spin echo modulation patterns (1987)

Romanelli, M. ; Kevan, L.

College Park, Md. : American Institute of Physics (AIP)

The Journal of Chemical Physics 86 (1987), S. 4369-4374

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ISSN: 1089-7690

Source: AIP Digital Archive

Topics: Physics , Chemistry and Pharmacology

Notes: Electron spin echo modulation patterns as modified by the presence of a completely asymmetric nuclear qudrupole interaction are evaluated by using a second order perturbation approach. The resulting modulated patterns are analyzed for S=1/2, I=1, and I=5/2 spin systems at different electron–nuclear distances and at different values of the asymmetry parameter. Comparison with the corresponding simulated patterns in the case of axially asymmetric nuclear quadrupole interaction shows remarkable differences both in the period and amplitude of the nuclear modulation.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1063/1.451899

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