ISSN:
1089-7690
Source:
AIP Digital Archive
Topics:
Physics
,
Chemistry and Pharmacology
Notes:
The lowest Σ bending vibration in the ArHCl van der Waals complex has been measured near 24 cm−1 by intracavity far infrared laser stark spectroscopy and FIR–microwave double resonance. In conjunction with the calculations of Hutson, the analysis of the molecular constants provides strong evidence that the intermolecular potential energy surface contains two minima at the ArHCl and ArClH linear geometries.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.452642