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Quadrupolar relaxation—an approach to rotational diffusion (1991)

Kontaxis, G. ; Sterk, H. ; Kalcher, J.

College Park, Md. : American Institute of Physics (AIP)

The Journal of Chemical Physics 95 (1991), S. 7854-7861

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ISSN: 1089-7690

Source: AIP Digital Archive

Topics: Physics , Chemistry and Pharmacology

Notes: The 7Li relaxational behavior of phenyl-lithium in isotropic solution has been investigated. The multiexponential quadrupolar relaxation dynamic facilitates the determination of the rotational diffusion constants together with the quadrupolar coupling constant, despite the zero average of the quadrupolar splitting on account of molecular tumbling. The rotational diffusion constants obtained are in very satisfactory agreement with those derived from our phenyl-lithium 13C relaxation studies.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1063/1.461314

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