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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Monatshefte für Chemie 99 (1968), S. 2494-2497 
    ISSN: 1434-4475
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Abstract Homogeneous acidification of solutions of NH4-, Na-, or K-thiovanadates yield the crystalline salts (NH4)2V3O8·1/2 H2O, Na3V5O12·8 H2O and K3V5O12·5 H2O. The latter two can be formulated as decavanadates(IV,V), containing the anion [V8 IVV2 VO24]6− and constituting new members of a series of already known anions with ratios of VIV∶VV from 2∶8 to 7∶3.
    Notes: Zusammenfassung Durch homogene Acidifizierung von NH4-, Na- bzw. K-Thiovanadatlösungen wurden die Salze (NH4)2V3O8·1/2 H2O, Na3V5O12·8 H2O und K3V5O12·5 H2O kristallin hergestellt. Die beiden letzteren lassen sich als Dekavanadate(IV, V) mit dem Anion [V8 IVV2 VO24]6− formulieren und bilden so weitere Glieder einer schon bekannten Reihe entsprechender Anionen mit dem VIV∶VV-Verhältnis 2∶8 bis 7∶3.
    Type of Medium: Electronic Resource
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