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  • 1
    Electronic Resource
    Electronic Resource
    Synthesen mit Nitrilen, 26. Mitt.: Die Amin-HCN-Austauschreaktion am 2-Dicyanmethylen-1,3-indandion (1970)
    Springer
    Monatshefte für Chemie 101 (1970), S. 1145-1148 
    Details
    ISSN: 1434-4475
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Abstract The reaction of 2-dicyanomethylen-1,3-indandione with diethylamine leads to 2-(diethylamino-cyanomethylen)-1,3-indandione, while HCN is eliminated. By NMR-spectroscopy at low temperature it can be shown that an instable intermediate with charge separation is formed.
    Notes: Zusammenfassung Die Umsetzung von 2-Dicyanmethylen-1,3-indandion mit Diäthylamin führt unter Abspaltung von HCN zum 2-(Diäthylamin-cyanmethylen)-1,3-indandion. Durch NMR-Spektroskopie bei tiefen Temperaturen kann ein instabiles Zwischenprodukt mit Ladungstrennung nachgewiesen werden.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00908560
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