ISSN:
1432-2099
Source:
Springer Online Journal Archives 1860-2000
Topics:
Biology
,
Physics
Notes:
Summary The NMR spectra of uracil and some of its derivatives have been investigated using deuterated dimethylsulfoxide as a solvent. The spectral positions of the peaks depend on the electron-attracting or -releasing strength of the substituents: rel. to uracil, the peaks were shifted upfleld in the case of the electron-releasing substituents andvice versa. A plot of the electron affinityvs. the H-3 position exhibits a straigth line. Addition of Cu2+ or other metal ions, such as Pe3+, Ni2+, Co2+, Zn2+, and Ag+, results in a splitting of the N-H protons, the distance of which turned out to be a linear relationship to the inverse electronegativity. K+, Na+, Mg2+, NH4 +, Cl−, NO3 −, SO4 2− had no effect at all. The effect of Cu2+ and the substituents as well seems to be mediated by the hydrogen bond formed between the uracil derivative and DMSO.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01189912
