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Laser-induced reactions of NO2 in the visible region (1985)

Umstead, M. E. ; Lloyd, S. A. ; Fleming, J. W. ; [et al.]

Springer

Applied physics 38 (1985), S. 219-224

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ISSN: 1432-0649

Keywords: 82.30 ; 82.50

Source: Springer Online Journal Archives 1860-2000

Topics: Physics

Notes: Abstract The reaction of NO2 with isobutane, induced by 488 nm laser radiation, to form 2-nitro-2-methylpropane has been investigated and the results computer-modeled according to two possible reaction mechanisms. The first scheme involves the direct abstraction of H from isobutane by vibronically excited NO2 (NO 2 *Δ ), and the second, abstraction by an intermediate NO3 radial produced by NO 2 *Δ +NO2. The modeling results strongly support the NO 2 *Δ scheme as the dominant reaction mechanism.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF00818047

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