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A theory of topological constraints in polymer networks (1987)

Heinrich, G. ; Straube, E.

Springer

Polymer bulletin 17 (1987), S. 247-253

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ISSN: 1436-2449

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics

Notes: Summary This paper presents an investigation of the dependence of harmonic-like topological constraints in entangled and moderately crosslinked polymer networks on segment and crosslink density and on the deformation of the sample. The approach is an extension of a theory developed for the highly crosslinked case and for polymer melts. The results are used to discuss the influence of topological constraints on the mechanical properties of different types of rubberelastic networks.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF00285357

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