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Conversion of 2-chloromaleylacetate in Alcaligenes eutrophus JMP134 (1993)

Vollmer, Martin Dominik ; Stadler-Fritzsche, Karin ; Schlömann, Michael

Springer

Archives of microbiology 159 (1993), S. 182-188

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ISSN: 1432-072X

Keywords: 2,4-Dichlorophenoxyacetate ; Maleylacetate reductase ; Chloride elimination ; Maleylacetate ; Chloromaleylacetate ; Alcaligenes eutrophus ; pJP4

Source: Springer Online Journal Archives 1860-2000

Topics: Biology

Notes: Abstract 2,4-Dichlorophenoxyacetate (2,4-D) in Alcaligenes eutrophus JMP134 (pJP4) is degraded via 2-chloromaleylacetate as an intermediate. The latter compound was found to be reduced by NADH in a maleylacetate reductase catalyzed reaction. Maleylacetate and chloride were formed as products of 2-chloromaleylacetate reduction, the former being funnelled into the 3-oxoadipate pathway by a second reductive step. There was no indication for an involvement of a pJP4-encoded enzyme in either the reduction or the dechlorination reaction.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF00250280

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