ISSN:
1572-8927
Keywords:
aluminum
;
silica
;
complexation
;
Raman
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract Raman spectroscopic measurements were performed on aqueous acid to neutral silica-bearing solutions (0.005 ≤ m Si ≤ 0.02, 0 ≤ pH ≤ 8) and Al–silica solutions at temperature from 20 to 150°C. At 20°C, the spectrum of silica-bearing solutions exhibits only the bands of water and a completely polarized band at 785 cm−1. This band is attributed to the ν1 band of the tetrahedral Si(OH)4 molecule. In $${\text{Si(OH)}}_{\text{4}} {\kern 1pt} {\kern 1pt} - {\kern 1pt} {\text{AlCl}}_3 {\kern 1pt} - {\kern 1pt} {\text{HCl}}$$ solutions, the intensity of this band decreases with increasing Al concentration, temperature, and pH. This decrease can be explained by the formation of an inner sphere complex between Al3+ and Si(OH)4 according to the reaction: $${\text{Al}}^{{\text{3 + }}} {\text{ + H}}_{\text{4}} {\text{SiO}}_{\text{4}}^{\text{0}} ({\text{aq}}){\text{ }} \Leftrightarrow {\text{ AlH}}_{\text{3}} {\text{SiO}}_{\text{4}}^{{\text{2 + }}} {\text{ + H}}^{\text{ + }} $$ The fraction of complexed silica deduced from raman spectroscopic measurements is in good agreement with that calculated for the similar solution compositions and temperatures using the complexation constant generated by Pokrovski et al. (23) from potentiometric measurements. At ambient temperature, the formation of aluminum silicate complex is weak and does not account for more than ca. 5 % of the total Al in most natural waters. As temperature increases, this complex becomes more significant and can dominate Al speciation in acid (pH ≤ 2) hydrothermal solutions.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1023/A:1021703408311
