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Activation of palladium acetate by water in the catalytic vinylation of carboxylic acids with vinyl acetate (1989)

Ketterling, A. A. ; Lisitsyn, A. S. ; Likholobov, V. A.

Springer

Reaction kinetics and catalysis letters 39 (1989), S. 405-409

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ISSN: 1588-2837

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology

Description / Table of Contents: Abstract Найдено, что добавки в реакционную смесь воды увеличивают начальную скорость винилирования пропионовой кислоты в присутствии ацетата палладия. Совместное введение воды и карбоксилата щелочного металла позволяет в десятки раз повысить активность катализатора, практически не снижая селективности.

Notes: Abstract Addition of water to the reaction mixture was found to enhance significantly the rate of vinylation of propionic acid in presence of a palladium acetate based catalysts, with selectivity of the reaction remaining almost unchanged.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF02071360

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