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Column chromatography of carrier-free Tc/III, IV/-TTA complexes (1984)

Okamoto, T. ; Omori, T. ; Yoshihara, K.

Springer

Journal of radioanalytical and nuclear chemistry 85 (1984), S. 245-251

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ISSN: 1588-2780

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology , Energy, Environment Protection, Nuclear Power Engineering

Notes: Abstract The chemical species of carrier-free technetium, which were extractable into a TTA-benzene solution on reduction of96TcO 4 − either with NaBH4 or concentrated HCl, were studied by means of silica gel chromatography. Elution peaks ascribed to the formation of Tc/tta/4 and Tc/tta/3 type complexes were observed. The latter complex was also synthesized by recoil effect of Ru/γ, p/Tc reactions in γ-irradiated Ru/tta/3.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF02164229

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