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  • 1
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract An interaction of electrochemical ideas with the approaches of solid state physics provides some interesting analogies and themes in which certain aspects of electrolyte solutions, solid semiconductors and ionic liquids can be discussed in a somewhat inter-related manner. Some of the fundamental properties of this wide range of materials (solid semiconductors, molten salts or aqueous (electrolyte) solutions) may be unified into a loose theme derived from the general notions of the band theory of solids and its analogue in electrolyte solutions, namely, the electron and proton levels of electrolytes. The concepts which would describe the intermeshing behaviour of these materials will be derived from: the band theory of semi-conductors; Gurney's ideas on the occupied and vacant proton levels in electrolyte solutions; Rose's approach to the electron energy levels in solids and electrolytes; Fuller's views on the conceptual analogies between semiconductors and electrolyte solutions; interpretation of molten salts put forward by Bockris and co-workers; and, finally, the industrial applications of Gurney's ideas made by Vermilyea in his interpretations of the corrosion of aluminium in water and the effect of various inhibitors on this corrosion reaction.
    Type of Medium: Electronic Resource
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