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An approach to channel type molecular structures. 1. Synthesis ofBouquet-shaped molecules based on an [18]-O6 polyether macrocycle (1992)

Jullien, Ludovic ; Lehn, Jean-Marie

Springer

Journal of inclusion phenomena and macrocyclic chemistry 12 (1992), S. 55-74

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ISSN: 1573-1111

Keywords: Polyether macrocycle ; molecular channel ; molecular bundle

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology

Notes: Abstract An approach to a transmembrane cation channel is described. It is based on the grafting of oxygen bearing side-chains on a macrocyclic polyether unit that constitutes the organizing core. The resulting species has a structure of overall bouquet shape. The synthesis of such a molecule .ℬ M 0 ,14a is described, together with that of its analogue bearing polymethylene side-chains ℬ M C ,14b. The physicochemical properties of these molecules indicate that they possess the features expected on the basis of their structure.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF01053855

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