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  • 1
    Electronic Resource
    Electronic Resource
    Hyperfine interactions 16 (1983), S. 1029-1031 
    ISSN: 1572-9540
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Clauser and Mössbauer [1] showed that the second order (in perturbation theory) magnetic hyperfine interaction, the so called “pseudoquadrupole inter-action”, in the169Tm Mössbauer effect can produce apparent isomer shifts. While they assumed two isolated singlets and simplified the coupling, we will show that the second order magnetic hyperfine coupling can be observed in general for any kind of crystalline electric field (CEF) wavefunctions, and that the coupling between many states must often be considered in calculating it. Furthermore since the first order magnetic coupling of the excited CEF states is important, the interaction is best accounted for by diagonalization of the full magnetic hyperfine and CEF Hamiltonian. Examples of the effects that may occur are presented.
    Type of Medium: Electronic Resource
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