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Copolymerization and interaction of acrylonitrile and indene (1989)

Mikhael, M. G. ; Mokhtar, S. M. ; Saad, G. R. ; [et al.]

Bognor Regis [u.a.] : Wiley-Blackwell

Journal of Polymer Science Part A: Polymer Chemistry 27 (1989), S. 185-191

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ISSN: 0887-624X

Keywords: Chemistry ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The donor-acceptor interaction of acrylonitrile (AN) with indene (In) has been investigated by means of ultraviolet spectroscopy and dielectric polarization measurements. The latter method yielded a value of 0.5 for the association constant of the charge-transfer-complex (CTC) and a 4.02 D for its dipole moment. The copolymerization of the two monomers was characterized by a tendency towards alternation when conducted in the bulk. This might be due to the participation of a weak CTC in the process of copolymerization. However, this tendency disappeared in polar solvents such as DMF.

Additional Material: 3 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/pola.1989.080270116

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