ISSN:
0887-624X
Keywords:
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Radical acrylamide telomerization was carried out with three fluorinated telogens, C6F13C2H4I, C6F13I, and C6F13-C2H4SH with AIBN as initiator. Transfer constants were determined to be 40 × 10-4, 550 × 10-4, and 6500 × 10-4, respectively. Reactions were carried out in butyronitrile, a solvent which also transfers to the growing chain. In the telomerization, the intervention of the solvent, whose transfer constant was also determined, is evaluated quantitatively. Thus the formation of side products, which may reach proportions on the order of 50% compared with the telomer expected, can be explained.
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/pola.1986.080241117