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  • 1
    Electronic Resource
    Electronic Resource
    Cage effects in recombination of allyl radicals in irradiated polyethylene. II. Cumulative reaction rates and decay kinetic processes (1983)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 21 (1983), S. 2003-2010 
    Details
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Hwang and Cheng have studied the recombination reaction of allyl radicals in irradiated polyethylene by including the effects of (i) diffusion of macroradicals by jumps of finite size in the crystalline phase and (ii) a caging reaction with a finite rate in the disordered region. In this work their results are used to analyze cumulative reaction rate data on the decay of allyl radicals in extended-chain and Marlex film polyethylene. The kinetic parameters obtained show the effects of reaction temperature, irradiation dose, and morphological differences.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1983.180211010
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