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Thermoelasticity of networks in swelling equilibrium with mixed diluents: Specific polymer-diluent interactions (1980)

Britton, A. T. ; Sullivan, J. L. ; Smith, K. J.

New York : Wiley-Blackwell

Journal of Polymer Science: Polymer Physics Edition 18 (1980), S. 537-546

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ISSN: 0098-1273

Keywords: Physics ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Physics

Notes: Thermoelasticity studies of poly(vinyl alcohol) networks swollen in aqueous glycol indicate that the effects of specific polymer-diluent interactions diminish at high swelling, much as in the situation of poly(vinyl alcohol) in pure water reported earlier. In 20% glycol, the ratio of the energy component fe of the force to the total force f was found to be -0.59 at high swelling. Swelling was controlled by the degree of network crosslinking. Evidence that fe/f could be determined under the condition of a null thermal expansion coefficient was not obtained; in fact, the contrary was indicated.

Additional Material: 1 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/pol.1980.180180313

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