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Notes on the statistics of polymer chains (1953)

Ullman, R. ; Hermans, J. J.

Hoboken, NJ : Wiley-Blackwell

Journal of Polymer Science 10 (1953), S. 559-576

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ISSN: 0022-3832

Keywords: Chemistry ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Physics

Notes: The configurations of flexible macromolecules are discussed with particular emphasis on some problems arising in the theory of the volume effect. The main points considered are: (1) the relationship between the Kuhn statistical chain element and the carbon bond length; (2) the assumption that a polymer chain is equivalent to a collection of independent beads normally distributed with respect to the center of gravity (“Gaussian gas” model); (3) the distribution of segments of a polymer chain with respect to the center of gravity; (4) the theory of the execluded volume for plane models of a polymer molecule; (5) the relationship between the excluded volume and the local density of polymer segments; (6) the influence of the solvent on the excluded volume; (7) polymer configurations and viscosity.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/pol.1953.120100607

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