ISSN:
0022-3832
Keywords:
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
The various stages employed in the production of a phenolformaldehyde cast resin are discussed. It is assumed that the chains formed during the condensation stage undergo a rearrangement upon acidification to yield roughly spherical, stabilized micelles. These micelles are concentrated by dehydration until coalescence begins. At this point the chains again rearrange and the resin becomes the continuous phase. Pronounced changes in the properties of the system are observed at this critical point. The effects produced by undercondensation, overcondensation, overdehydration, etc. are mentioned briefly. The ionizable components, by determining the interfacial pH during the curing stage, are shown to be directly related to the rate of cure, stability, color, light transmissibility, etc. of the cured casting. Transparent castings are expected only when an ionizable component of the proper refractive powers is oriented at the interface. An examination of the immediately available data provides a lead to the future changes that can be expected as aging progresses.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/pol.1953.120100102
