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  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 16 (1972), S. 1967-1982 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A constitutive equation, previously derived for dilute, monodisperse solutions of linear macromolecules, is extended to include polydisperse solutions. This result, which represents a coupling of continuum and molecular theory, realistically portrays the effects of molecular weight and molecular weight distribution on mechanical behavior. Intrinsic viscosity-shear rate data are well described, and with certain semiempirical modifications the equation also fits normal stress and dynamic viscosity data for slightly more concentrated solutions. Some unusual effects associated with the characterization of macromolecular degradation, in studies of turbulent drag reduction, are also explained.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
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