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Dynamic mechanical studies of endgroup-modified polystyrene (1974)

Fellers, J. F. ; Rahbar-Semanani, M.

New York : Wiley-Blackwell

Journal of Polymer Science: Polymer Chemistry Edition 12 (1974), S. 2035-2043

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ISSN: 0360-6376

Keywords: Physics ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Polystyrenes having both modified and unmodified endgroup structures were synthesized. These polystyrenes were then subjected to dynamic mechanical testing below their glass transition temperature. The modified structures were shown to influence the β transition of polystyrene. While the mechanism of this secondary transition has been speculated but never unequivocally substantiated in the past, the evidence presented here strongly support the idea that the β transition of polystyrene arises from chain-end motions.

Additional Material: 5 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/pol.1974.170120917

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