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Lipase catalyzed transesterification of 2-substituted 3-hydroxy esters (1998)

Kaga, Harumi ; Hirosawa, Kunio ; Takahashi, Tomiki ; [et al.]

New York, NY [u.a.] : Wiley-Blackwell

Chirality 10 (1998), S. 693-698

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ISSN: 0899-0042

Keywords: Pseudomonas cepacia ; lipase PS ; transesterification ; kinetic resolution ; 2-substituted 3-hydroxy ester ; Chemistry ; Organic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Kinetic resolution of 2-substituted 3-hydroxy esters was examined by lipase PS catalyzed transesterification using vinyl acetate as an acyl donor. Resolution of (±)-syn- and -anti-1a, -1e possessing a small methyl group at the C-3 position was accomplished enantioselectively. The outcome of the resolution seems to be related to the differences in size of the substituents at the stereocenter bearing a secondary hydroxy group. Chirality 10:693-698, 1998. © 1998 Wiley-Liss, Inc.

Additional Material: 1 Ill.

Type of Medium: Electronic Resource

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