ISSN:
0894-3230
Keywords:
Organic Chemistry
;
Physical Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
1H and 13C NMR data for 2-diethylaminomethyl-3,4,6-tri- and -tetrachlorophenols in CH2Cl2 solutions at a variety of temperatures are reported. The results are consistent with intramolecular hydrogen bonding and proton transfer as shown in the structure 3. Concentration dependence of the NMR data for the perchloro compound shows an additional hydrogen bonding process attributed to the solute self-association. The 1H, 13C and 15N NMR data support the proposed proton transfer structure.
Additional Material:
4 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/poc.610080704