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  • 1
    ISSN: 0044-2313
    Keywords: Thiazyltrifluoride ; Thiazyldifluoridedimethylamide ; metal complexes ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Thiazyltrifluoride NSF3 and Thiazyldifluoridedimethylamide NSF2NMe2: Ligands in Organometallic ChemistryFrom the reaction of [Re(CO)5SO2]+AsF6- (1) and [CpFe(CO)2SO2]+AsF6- (6) with NSF3 (2) and NSF2NMe2 (4) the complexes [Re(CO)5NSF3]+AsF6- (3), [Re(CO)5NSF2NMe2]+AsF6- (5), [CpFe(CO)2NSF3]+AsF6- (7), and [CpFe(CO)2NSF2NMe2]+AsF6- (8) were obtained. The compounds have been characterised by X-ray crystallography, the ligand properties of 2 and 4 are discussed.
    Notes: Durch Umsetzung von [Re(CO)5SO2]+AsF6- (1) und [CpFe(CO)2SO2]+AsF6- (6) mit NSF3 (2) und NSF2NMe2 (4), wurden die Komplexe [Re(CO)5NSF3]+AsF6- (3), [Re(CO)5NSF2NMe2]+AsF6- (5), [CpFe(CO)2NSF3]+AsF6- (7) und [CpFe(CO)2NSF2NMe2]+AsF6- (8) dargestellt und durch Kristallstrukturanalysen charakterisiert. Die Ligandeneigenschaften von 2 und 4 werden diskutiert.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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