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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 613 (1992), S. 98-104 
    ISSN: 0044-2313
    Keywords: Barium fluoride  -  aluminium fluoride system ; liquid-solid phase diagram ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Das binäre System BaF2/AlF3Das System BaF2/AlF3 wird röntgenographisch sowie mittels DTA untersucht und das fest-flüssig Phasendiagramm aufgestellt. Es liegen fünf ternäre Fluoride vor: trimorphes BaAlF5, Ba3Al2F12, Ba5Al3F19, polymorphes Ba3AlF9 und Ba5AlF13. Neutronen-thermodiffraktometrische Versuche wurden zur Analyse einiger Teile des Diagramms durchgeführt. Die Gitterparameter der Fluoride werden angegeben und die Ergebnisse diskutiert und mit denen vorhergehender Arbeiten verglichen.
    Notes: The system BaF2/AlF3 is investigated by X-ray and D.T.A., and the liquid-solid phase diagram is established. Five ternary fluorides are disclosed: trimorphic BaAlF5, Ba3Al2F12, Ba5AlF19, polymorphic Ba3AlF9 and Ba5AlF13. Neutron thermodiffractometry experiments are performed to specify some parts of the diagram. The cell parameters of the fluorides are given and the results are discussed and compared with those of the previous works.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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