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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 591 (1990), S. 214-220 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Reaction of the Two-Component System Trialkylphosphite/Tetrachloromethane with Bifunctional NucleophilesBifunctional nucleophiles such as 1,2-dioles and 2-aminoalcohols react with the two-component system triethylphosphite/tetrachloromethane to cyclic, acyclic and spirocyclic PV compounds. Reaction route and composition of the product mixtures are characterized by the competition of ligand exchange and cyclisation reactions.
    Notes: Bifunktionelle Nucleophile wie 1,2-Diole und 2-Aminoalkohole reagieren mit dem Zweikomponentensystem Triethylphosphit/Tetrachlormethan zu cyclischen, acyclischen und spirocyclischen PV-Verbindungen. Kennzeichnend für den Reaktionsverlauf und die Zusammensetzung der Reaktionsgemische ist die Konkurrenz von Ligandenaustausch- und Ringschlußreaktionen.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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