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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 569 (1989), S. 169-176 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Komplexe Kupfer(II)-fluoride. X. Das ternäre System BaF2—CuF2—InF3Das flüssig-fest-Gleichgewichtsdiagramm des InF3—BaF2-Systems wird mittels DTA bestimmt. Die Fluoride BaInF5, das dimorphe Ba3In2F12 und auch eine kubische Phase Ba1-xInxF2+x, deren Struktur sich von der des BaF2 ableitet, wurden gefunden. Die zwei Formen des Ba3In2F12 geben feste Lösungen. Ein isothermer Ausschnitt des ternären Systems BaF2—CuF2—InF3 bei 540°C wird angegeben. Er zeigt die Existenz nur eines quaternären Fluorides: tetragonales BaCuInF7.
    Notes: The liquid-solid equilibria diagram of the InF3—BaF2 system is established by D.T.A. The fluorides BaInF5, the dimorphic Ba3In2F12, and also a cubic phase Ba1-xInxF2+x, the structure of which derives from that of BaF2, are disclosed. The two forms of Ba3In2F12 give solid solutions. An isothermal section of the ternary system BaF2—CuF2—InF3 at 540°C is given. It shows the existence of only one quaternary fluoride: tetragonal BaCuInF7.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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