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  • 1
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Contributions to the Chemistry of Phosphorus Compounds with Adamantane Structure. XIV. Crystal Structure of a 3, 5-Diphenyl-1, 2, 4-dithiazolium Salt with the Cage-like Anion [P4NS9]The compound 3, 5-Diphenyl-1, 2, 4-dithiazolium 1, 3, 5, 7-pentathioxo-10-aza-2, 4, 6, 8, 9-pentathia-1α5,3λ5,5λ5,7λ5-tetraphosphatricyclo[3.3.1.13,7]decanide has been prepared by the reaction of P4S10 with benzonitrile. It crystallizes in the triclinic space group P1 with a = 9.914 Å, b = 15.025 Å, c = 9.186 Å, α = 100.48°, β = 99.90°, γ = 90.66°, and Z = 2. The anion has the structure of a P4S10-like cage, in which one P—S—P group is replaced by the P—N—P group.
    Notes: 3, 5-Diphenyl-1, 2, 4-dithiazolium-1, 3, 5, 7-tetrathioxo-10-aza-2, 4, 6, 8, 9-pentathia-1λ5,3λ5,5λ5,7λ5-tetraphospha-tricyclo[3.3.1.13,7]decanid entsteht bei der Reaktion von P4S10 mit Benzonitril. Die Verbindung kristallisiert in der triklinen Raumgruppe P1 mit a = 9, 914 Å b = 15,025 Å, c = 9,186 Å, α = 100,48°, β = 99,90° γ = 90,66° und Z = 2. Das Anion hat die Struktur eines P4S10-ähnlichen Käfigs, in dem eine PSP-durch eine PNP-Gruppe ersetzt ist.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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