ISSN:
0044-2313
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
On Li2NiF5 and Na2NiF6.For the first time pure samples of Na2[NiF6] (carmine red; monoklinic, a = 7.564, b = 5.686, c = 5.378 Å, β = 92.28°; Z = 2) have been obtained by pressure fluorination (monel-autoklavs, pF2 = 300 bar, 300°C, 18h) and indexed.Similarly (monel-autoklavs, pF2 = 300 bar, 300°C, 10h) samples of Li2NiF5 (violet; monoclinic, a = 9.788, b = 4.886, c = 9.966 Å; β = 135.56°; Z = 4) have been prepared.
Notes:
Durch Fluorierung unter erhöhtem Druck (Monel-Autoklav, PF2 = 300 bar, 300°C, 18 h) konnten erstmals reine Proben von Na2[NiF6] (karminrot; monoklin, a = 7,564, b = 5,686, c = 5,378 Å; β = 92,28°; Z = 2) dargestellt und indiziert werden.Ebenfalls unter erhöhtem Fluordruck (Monel-Autoklav, pF2 = 300 bar, 300°C, 10h) wurden violette Proben von Li2NiF5 (monoklin, a = 9,788, b = 4,886, c = 9,966 Å; β = 135,56°; Z = 4) erhalten.
Additional Material:
4 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19824900102
