ISSN:
0044-2313
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Polynuclear Cobalt Complexes. IV. Preparation and Structure of [(papd)Co(O2)Co(papd)](S2O6)(NO3)2 · 4 H2OThe binuclear peroxo complex [(papd)Co(O2)Co(papd)](S2O6)(NO3)2 · 4 H2O I crystallizes in the triclinic space group P1. Lattice constants are a = 9.405(4), b = 9.270(4), c = 12.218(6)Å, α = 89.58(5), β = 99.08(6), γ = 114.79(5)° for Z = 1. The binuclear cation has a center of symmetry, so the Co—O—O—Co unit is planar. Three chelate rings have a common plane, the ligand configuration is δ.
Notes:
Der binucleare Peroxokomplex [(papd)Co(O2)Co(papd)](S2O6(NO3)2 · 4 H2O I kristallisiert in der triklinen Raumgruppe P1. Die Gitterkonstanten sind a = 9,405(4), b = 9,270(4), c = 12,218(6) Å, α = 89,58(5), β = 99,08(6), γ = 114,79(5)° für Z = 1. Das Kation liegt auf einem Symmetriezentrum, die Co—O—O—Co-Einheit ist planar. Drei Chelatringe liegen in einer gemeinsamen Ebene, die Ligandkonfiguration ist δ.
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19804610109
