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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 450 (1979), S. 67-69 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Komplexchemie von Niob und Tantal. XVIII. Peroxo-EDTA Niobate(V) und Tantalate(V)Darstellung und Eigenschaften von Peroxo-Ethylendiamintetraacetatoniobat(V) und -tantalat(V) werden beschrieben. Diese stabilen und kristallinen Komplexe kann man aus Wasser und Wasserstoffperoxid rekristallisieren. Die chemischen und spektralen Untersuchungen stimmen mit der Formel M3I[MV (O2)3EDTA] nH2O2, MI = K, NH4; MV = Nb, Ta; m ≤ 1, überein. Niob und Tantal Verbindungen sind isomorph.
    Notes: Preparation and Properties of peroxoethylenediaminetetraacetato niobates(V) and tantalates(V) are reported. These stable, crystalline complexes can be recrystallized from aqueous and hydrogen peroxide solutions. According to chemical and spectral evidence the complexes correspond to the formula M3I[MV (O2)3EDTA] nH2O2, MI = K, NH4; MV = Nb, Ta; n ≤ 1. Niobium and tantalum compounds are isomorphous.
    Type of Medium: Electronic Resource
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