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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 428 (1977), S. 145-150 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: On the Preparation and Constitution of the Compound 3 CaO · 3 GeO2 · H2OIn the temperature range from 100-∽450°C it is possible to prepare under hydrothermal conditions from equimolar mixtures of CaO and GeO2 the compound 3 CaGeO3 · H2O. By n.m.r. measurements of the solid compound it is shown, that there are only OH groups and no molecular water. It seems to be probable that this compound is a trigermanate of the formula Ca3H2 [Ge3O10].
    Notes: Aus äquimolaren Gemischen aus CaO und GeO2 läßt sich im Temperaturbereich von 100 bis ∽450°C unter hydrothermalen Bedingungen die Verbindung 3 CaGeO3 · H2O herstellen. Mit Hilfe von Kernresonanzmessungen an der festen Substanz wird nachgewiesen, daß nur OH-Gruppen vorliegen und kein molekulares Wasser vorhanden ist. Es wird wahrscheinlich gemacht, daß die Verbindung ein saures Trigermanat der Formel Ca3H2[Ge3O10] ist.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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