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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 425 (1976), S. 67-80 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Crystal Chemistry of the Alkali Salts of the Main Group V Element TetrathioacidsThe anhydrous tetrathioantimonates of K+, NH4+, and Na+ crystallize cubic in the (NH4)3SbS4-structure type. The analogous tetrathioarsenates and -phosphates form the (NH4)3AsS4-structure type. In the formation of these two different structures the density of the atomic packing is essential.
    Notes: Die wasserfreien Tetrathioantimonate von K+, NH4+ und Na+ kristallisieren kubisch im (NH4)3SbS4-Typ, während bei den bisher bekannten Alkalitetrathioarsenaten und -phosphaten der (NH4)3AsS4-Typ beobachtet wird. Die Ausbildung der beiden unterschiedlichen Strukturtypen wird auf Packungseffekte zurückgeführt.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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