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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 419 (1976), S. 48-57 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Chemistry of Silicon-Nitrogen Compounds. CXXXII. Derivatives of the 1,2,4-Trisila-3,5-diaza-cyclopentane Ring SystemThe derivatives B1-B6 of the title ring system could be prepared for the first time by reaction of 1,2-bis(alkylamino)disilanes (A1, A2) with dihalosilanes (Scheme 1). They were transformed by additional reactions with methanol or amines into B7-B9. The Cl2Si derivative B2 is characterized by an unusual stability against aqueous solutions.
    Notes: Durch Reaktion von Dihalogensilanen mit 1,2-Bis(alkylamino)disilanen (A1, A2) konnten die Derivate B1-B6 des Titelringsystems und durch deren weitere Umsetzung die Verbindungen B7-B9 erstmalig dargestellt werden (Schema 1). B2 zeichnet sich durch eine ungewöhnliche Stabilität gegenüber neutralen wäßrigen Lösungen aus.
    Additional Material: 4 Tab.
    Type of Medium: Electronic Resource
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